ORIGINAL_ARTICLE
Synthesis, Characterization, and Antibacterial Activity of ZnO Nanoparticles from Organic Extract of Cola Nitida and Cola Acuminata Leaf
The study aimed at the synthesis and antibacterial activity of ZnO nanoparticles (NPs) from organic extracts of Cola nitida and Cola acuminata leaf using zinc chloride (ZnCl2) and zinc acetate dihydrate [Zn(CH3COO)2∙2H2O] as precursors on selected Gram positive and Gram negative microbes: Staphylococcus aureus, Exiguobacterium aquaticum, (Gram +ve) and Escherichia coli, Klebsielia pneumonia, Acinetobacter baumanni (Gram –ve). Spherical and flake-like nanostructures were recorded by Scanning Electron Microscopy (SEM) for C. acuminata and C. nitida respectively for the two precursors used. The average particle size and crystallite size determined by Transmission Electron Microscopy (TEM) and X-ray Diffraction (XRD) for C. acuminata and C. nitida were in the range of 32.15-43.26 nm; 69.12-84.26 nm and 14.69-17.12 nm; 23.68-23.96 nm respectively. Energy-dispersive X-ray spectroscopy (EDX), UV- visible spectroscopy (UV-vis), Atomic Absorption Spectroscopy (AAS) and Fourier-transform infrared spectroscopy (FT-IR) techniques were used to observe the purity and surface functional groups of the samples. Spectra peaks at 440-458 cm-1 and 364-370 nm confirmed the presence of ZnO in the samples by FT-IR and UV-vis, whereas AAS at 213.9 nm wavelength further confirmed elemental zinc with a percentage atomic weight of 71.37% as against 69.50%, 18.8% and 11.1% for Zinc, Oxygen and Carbon by EDX. Data from the antibacterial activity studies show an increase in inhibition rate as concentration of the ZnO NPs increases in concentration from 25-1000 ppm. ZnO NPs from the two extracts recorded the highest inhibition rate in Acinetobacter baumanni of approximately 88% and 49% using ZnCl2 and Zn(CH3COO)2∙2H2O respectively.
https://www.ijnnonline.net/article_39978_bf11680bdacc77e771154b715d5eb5b9.pdf
2020-05-01
73
89
Precursor
Functional groups
microscopy
nanostructure
Spectroscopy.
A. E.
Aquisman
asare12@gmail.com
1
Resource Chemistry Program, Faculty of Resource Science and Technology, Universiti Malaysia Sarawak 94300, Kota Samarahan, Sarawak, Malaysia.
AUTHOR
B. S.
Wee
swboon1@unimas.my
2
1Resource Chemistry Program, Faculty of Resource Science and Technology, Universiti Malaysia Sarawak 94300, Kota Samarahan, Sarawak, Malaysia.
AUTHOR
S. F.
Chin
chin88@unimas.my
3
1Resource Chemistry Program, Faculty of Resource Science and Technology, Universiti Malaysia Sarawak 94300, Kota Samarahan, Sarawak, Malaysia.
AUTHOR
D. E.
Kwabena
kobladodzie01@yahoo.com
4
Resource Chemistry Program, Faculty of Resource Science and Technology, Universiti Malaysia Sarawak 94300, Kota Samarahan, Sarawak, Malaysia.
LEAD_AUTHOR
K. O.
Michael
kyene_odoi@gmail.com
5
Department of Pharmaceutics, Centre for Plant Medicine Research, Mampong-Akuapem, Ghana.
AUTHOR
T.
Bakeh
tomib@unimas.my
6
Resource Chemistry Program, Faculty of Resource Science and Technology, Universiti Malaysia Sarawak 94300, Kota Samarahan, Sarawak, Malaysia.
AUTHOR
Sh.
Semawi
shafri11@unimas.my
7
Resource Chemistry Program, Faculty of Resource Science and Technology, Universiti Malaysia Sarawak 94300, Kota Samarahan, Sarawak, Malaysia.
AUTHOR
D. S.
Sylvester
dapaahsamuel@gmail.com
8
St. Joseph’s College of Education, Bechem, Brong Ahafo Region, Ghana.
AUTHOR
Jones, K. E., Patel, N. G., Levy, M. A., Storeygard, A., Balk, D., Gittleman, J. L., Daszak, P., (2008). “Global trends in emerging infectious diseases”, Nature, 451(7181): 990–993.
1
Khan, S. T., Musarrat, J., Al-Khedhairy, A. A., (2016). “Countering drug resistance, infectious diseases, and sepsis using metal and metal oxides nanoparticles, current status”, Colloids Surf B Biointerfaces, 146: 70–83.
2
Kumar, R.., Umar, A., Kumar, G., Nalwa, H. S., (2017). “Antimicrobial properties of ZnO nanomaterials: a review”, Ceram Int., 43: 3940–3961.
3
Yah, C. S., Simate, G. S., (2015). “Nanoparticles as potential new generation broad spectrum antibacterial agents”, DARU Journal of Pharmaceutical Sciences, 23(1): 43.
4
Vimbela, G. V., Ngo, S. M., Fraze, C., Yang, L., Stout, D. A., (2017). “Antibacterial properties and toxicity from metallic nanomaterials”, International journal of nanomedicines, 12: 3941.
5
Nowack, B., Bucheli, T. D., (2007). “Occurrence, behavior and effects of nanoparticles in the environment”, Environmental pollution, 150(1): 522.
6
Bhattacharya, R., Mukherjee, P., (2008). “Biological properties of naked metal nanoparticles”, Advanced Drug Delivery Reviews, 60(11): 1289-1306.
7
Sharma, V. K., Yngard, R. A., Lin, Y., (2009). “Silver nanoparticles: green synthesis and their antibacterial activities”, Advances in colloid and interface science, 145(1-2): 83-96.
8
Shah, M., Fawcett, D., Sharma, S., Tripathy, S. K., Poinern, G. E. J., (2015). “Green synthesis of metallic nanoparticles via biological entities”, Materials, 8(11): 7278-7308.
9
Stankic, S., Suman, S., Haque, F., Vidic, J., (2016). “Pure and multi metal oxide nanoparticles: synthesis, antibacterial and cytotoxic properties”, J. Nanobiotechnol., 14(1): 73.
10
Nel, A., Xia, T., Mädler, L., Li, N., (2006). “Toxic potential of materials at the nanolevel”, Science, 311(5761): 622-627.
11
Singh, B. N., Rawat, A. K. S., Khan, W., Naqvi, A. H., Singh, B. R., (2014). “Biosynthesis of stable antioxidant ZnO nanoparticles by Pseudomonas aeruginosa rhamnolipids”, PLoS One, 9(9): 106937.
12
Peralta-Videa, J. R., Huang, P. Y., Parsons, J., Zhao, L., Lopez-Moreno, L., Hernandez-Viezcas, J. A., Gardea-Torresdey, J. L., (2016). “Plant-based green synthesis of metallic nanoparticles: scientific curiosity or a realistic alternative to chemical synthesis?”, Nanotechnol Environ Eng., 1(1): 4.
13
Hu, S-H., Chen, Y-C., Hwang, C-C., Peng, C-H., Gong, D-C., (2010). “Development of a wet chemical method for the synthesis of arrayed ZnO nanorods”, J. Alloy. Comp., 500 (2): L17–L21.
14
Wang, A., Ng, H. P., Xu, Y., Li, Y., Zheng, Y., Yu, J., Han, F., Peng, F., Fu, L., (2014). “Gold nanoparticles: synthesis, stability test, and application for the rice growth”, J. Nanomater., Article ID 451232.
15
Chen, Y., Zhang, C., Huang, W., Situ, Y., Huang, H., (2015). “Multimorphologies nano-ZnO preparing through a simple solvothermal method for photocatalytic application”, Mater. Lett., 141: 294–297.
16
Tien, H. N., Khoa, N., Hahn, S. H., Chung, J. S., Shin, E. W., Hur, S. H., (2013). “One-pot synthesis of a reduced graphene oxide – zinc oxide sphere composite and its uses as a visible light photocatalyst”, Chem. Eng. J., 229: 126–133.
17
Khorsand, Z. A., Wang, H. Z., Yousefi, R., Moradi, G. A., Ren, Z. F., (2013). “Sonochemical synthesis of hierarchical ZnO nanostructures”, Ultrason. Sonochem., 20 (1): 395–400.
18
Omri, K., Najeh, I., Dhahri, R., El Ghoul, J., El mir, L., (2014). “Effects of temperature on the optical and electrical properties of ZnO nanoparticles synthesized by sol-gel method”, Microelectron. Eng., 128: 53–58.
19
Khorsand, Z. A., Abrishami, M. E., Abd Majidi, W. H., Yosefi, R., Hosseini, S. M., (2011). “Effects of annealing temperature on some structural and optical properties of ZnO nanoparticles prepared by a modified sol-gel combustion method”, Ceram. Inter., 37(1): 393–398.
20
Wang, Y., Zhang, C., Bi, S., Luo, G., (2010). “Preparation of ZnO nanoparticles using the direct precipitation method in a membrane dispersion micro-structured reactor”, Powder Technol., 202(1-3): 130–136.
21
Sundrarajan, M., Ambika, S., Bharathi, K., (2015). “Plant-extract mediated synthesis of ZnO nanoparticles using Pongamia pinnata and their activity against pathogenic bacteria”, Adv. Powder Technol., 26: 1294-99.
22
Olad, A., Ghazjahaniyan, F., Nosrati, R., (2018). “A Facile and Green Synthesis Route for the Production of Silver Nanoparticles in Large Scale”, Int. J. Nanosci. Nanotechnol., 14(4): 289-296.
23
Geoprincy, G., Vidhya srri, B. N., Poonguzhali, U., Nagendra, N. G., Renganathan, S., (2014). “A review on green synthesis of silver nanoparticles”, Asian J. Pharm. Clin. Res., 6(1): 8–12.
24
Ahmed, S., Ahmad, M., Swami, B. L., Ikram, S., (2016). “A review on plants extract mediated synthesis of silver nanoparticles for antimicrobial applications: a green expertise”, J. Adv Res., 7(1): 17–28.
25
Soltanabad, M. H., Bagherieh-Najjar, M. B., Baghkheirati, E. K., Mianabadi, M., (2018). “Ag-Conjugated Nanoparticle Biosynthesis Mediated by Rosemary Leaf Extracts Correlates with Plant Antioxidant Activity and Protein Content”, Int. J. Nanosci. Nanotechnol., 14(4): 319-325
26
Ghanbari, M., Bazarganipour, M., Salavati-Niasari, M., (2017). “Photodegradation and removal of organic dyes using cui nanostructures, green synthesis and characterization”, Separation and Purification Technology, 173: 27-36,
27
Mohammadi-Aloucheh, R., Habibi-Yangjeh, A., Bayrami, A., Latifi-Navid, S., Asadi, A., (2018). “Enhanced anti-bacterial activities of ZnO nanoparticles and ZnO/CuO nanocomposites synthesized using Vaccinium arctostaphylos L. fruit extract”, Artificial Cells, Nanomedicine, and Biotechnology, 46(1): 1200-1209.
28
Santhoshkumar, J., Kumar, V. S., Rajeshkumar, S., (2017). “Synthesis of zinc oxide nanoparticles using plant leaf extract against urinary tract infection pathogen”, Resource-Efficient Technologies, 3, 459–465.
29
Fatimah, I., Aftrid, Z. H. V. I., (2019). “Characteristics and antibacterial activity of green synthesized silver nanoparticles using red spinach (Amaranthus tricolor L.) leaf extract”, Green Chem. Lett. and Revs., 12(1): 25–30.
30
Umar, H., Kavaz, D., Rizaner, N., (2019). “Biosynthesis of zinc oxide nanoparticles using Albizia lebbeck stem bark, and evaluation of its antimicrobial, antioxidant, and cytotoxic activities on human breast cancer cell lines”, Int. J. Nanomed., 14: 87–100
31
Rotimi, L, Ojemaye, M. O., Okoh, O. O., Sadimenko, A., Okoh, A. I., (2019). Synthesis, characterization, antimalarial, antitrypanocidal and antimicrobial properties of gold nanoparticle, Green Chem. Lett and Revs., 12(1): 61–68
32
Droepenu, E. K., Asare, E. A., (2019). “Morphology of green synthesized ZnO nanoparticles using low temperature hydrothermal technique from aqueous Carica papaya extract”, Nanoscience and Nanotechnology, 9(1): 29-36.
33
Divya, M. J., Sowmia, C., Joona, K., Dhanya, K. P., (2013). “Synthesis of zinc oxide nanoparticles from Hibiscus rosa-sinensis leaf extract and investigation of its antimicrobial activity”, Res. J. Pharm. Biol. Chem., 4(2): 1137-1142.
34
Dobrucka, R., Dugaszewska, J., (2015). “Biosynthesis and antibacterial activity of ZnO nanoparticles using Trifolium pratense flower extract”, Saudi J. of Biological Sci., 23(4): 517-523.
35
Shah, R. K., Boruah, F., Parween, N., (2015). “Synthesis and Characterization of ZnO Nanoparticles using Leaf Extract of Camellia sinesis and Evaluation of their Antimicrobial Efficacy”, Int. J. Curr. Microbiol. App. Sci., 4(8): 444-450
36
Sundaramurthy, N., Parthiban, C., (2015). “Biosynthesis of copper oxide nanoparticles using Pyrus pyrifolia leaf extract and evolve the catalytic activity”, Int. Res. J. of Eng. and Technol. (IRJET), 2(6), 332-338.
37
Reddy, L. S., Nisha, M. M., Joice, M., Shilpa, P. N., (2014). “Antibacterial activity of zinc oxide (ZnO) nanoparticle against Klebsiella pneumonia”, Pharmaceutical biology, 52(11): 1388-1397.
38
http://en.wikipedia.org/wiki/kolanut
39
Jayeola, C. O., (2001). “Preliminary studies on the use of kolanuts (Cola nitida) for soft drink production”, J. Food Technol. Afr., 6(1): 25-26.
40
Attfield, J., (1865). “On the food value of the kolanut – a new source of theine”, Pharm. J., 6: 457.
41
Blades, M., (2000). “Functional foods or neutraceutical”, Nutr. Food Sci., 30(2): 73-75.
42
Naczk, M., Shahidi, F., (2006). “Phenolics in cereals, fruits and vegetables: Occurrence, extraction and analysis”, J. Pharm. Biomed. Anal., 41: 1523–1542.
43
Umaru, I. J., Fasihuddin, B. A., Otitoju, O. O., Hauwa, A. U., (2018). “Phytochemical Evaluation and Antioxidant Properties of Three Medicinal Plants Extracts”, Med. & Anal. Chem. Int. J. Phytochem. Eval., 2(2): 1-8.
44
Yang, K., Lin, D., Xing, B., (2009). “Interactions of humic acid with nanosized inorganic oxides”, Langmuir, 25(6): 3571–3576.
45
Umaru, I. J., Fasihuddin, A. B., Zaini, B. A, Umaru, H. A., (2018b). “Antibacterial and cytotoxic actions of chloroform crude extract of Leptadenia hastata(pers)Decnee”, Clinical Medical Biochem., 4: 1-4.
46
Shadrokh, Z., Yazdani, A., Eshghi, H., (2017). “Study on Structural and Optical Properties of Wurtzite Cu2ZnSnS4 Nanocrystals Synthesized via Solvothermal Method”, Int. J. Nanosci. Nanotechnol., 13(4): 359-366.
47
Divya, M. J., Sowmia, C., Joona, K., Dhanya, K. P., (2013). “Synthesis of zinc oxide nanoparticle from Hibiscus rosa-sinensis leaf extract and investigation of its antimicrobial activity”, Res. J. Pharm. Biol. Chem. Sci., 4(2): 1137–1142.
48
Fakhari, S., Jamzad, M., Fard, H. K., (2019). “Green synthesis of zinc oxide nanoparticles: a comparison”, Green Chem. Lett and Revs., 12(1): 19–24
49
Geetha, A., Sakthivel, R., Mallika, J., Kannusamy, R., Rajendran, R., “Green synthesis of antibacterial zinc oxide nanoparticles using biopolymer Azadirachta indica Gum”, Orient. J. Chem., 2016; 32: 955-963.
50
Zheng, Y., Fu, L., Han, F., Wang, A., Cai, W., Yu, J., Yang, J., Peng, F., (2015). “Green biosynthesis and characterization of zinc oxide nanoparticles using Corymbia citriodora leaf extract and their photocatalytic activity”, Green Chem. Lett. and Revs., 8(2): 59–63.
51
Daphedar, A., Taranath, T. C., (2018). “Green synthesis of zinc nanoparticles using leaf extract of Albizia saman (Jacq.) Merr. and their effect on root meristems of Drimia indica (Roxb.) Jessop”, Caryologia., 71: 93-102.
52
Khatami, M., Alijani, H. Q., Heli, H., Sharifi, I., (2018). “Rectangular shaped zinc oxide nanoparticles: Green synthesis by Stevia and its biomedical efficiency”, Ceram. Int., 44: 15596-602.
53
Anvekar, T. S., Chari, V. R., Kadam, H., (2017). “Green Synthesis of ZnO Nano Particles, its Characterization and Application”, Mater. Sci. Res. India, 14(2): 153-157.
54
Gowsalya, V., Santhiya, E., Chandramohan, K., (2017). “Synthesis, characterization of ZnO nanoparticles from Thespesia populnea”, Indian J. Appl. Res., 7(10): 542-543.
55
Shankar S, Rhim J W., (2017). “Facile approach for large-scale production of metal and metal oxide nanoparticles and preparation of antibacterial cotton pads”, Carbohydr Polym., 163: 137–145.
56
Soosen, S. M., Lekshmi, B., George, K. C., (2009). “Optical properties of ZnO nanoparticles”, Academic Rev., 57-65.
57
Nagarajan, S., Arumugam, K. K., (2013). “Extracellular synthesis of zinc oxide nanoparticle using seaweeds of gulf of Mannar”, India. J. Nanobiotechnol., 11: 39.
58
Divyapriya, S., Sowmia, C., Sasikala, S., (2014). “Synthesis of zinc oxide nanoparticles and antimicrobial activity of Murraya koenigi”, World J. Pharm Sci., 3(12): 1635-1645.
59
ORIGINAL_ARTICLE
Comparison of Binary and Ternary Compositions of Ni-Co-Cu Oxides/VACNTs Electrodes for Energy Storage Devices with Excellent Capacitive Behaviour
Electrochemical performance of binary and ternary oxides composed of Ni, Co and Cu produced over a 3-dimensional substrate of vertically aligned carbon nano-tubes (VACNT) as electrodes for aqueous energy sources, is reported and compared in this paper. VACNTs were fabricated inside a DC-plasma enhanced chemical vapor deposition chamber and composite materials fabricated by thermal decomposition method on the surface of VACNT electrodes. XRD, Raman and electron microscopy tests were used to verify electrodes proper composition and interface between the electrodes substrate and active material. Cyclo-voltammetry experiments were done over electrodes and Co-Cu oxide/VACNT electrode found to have the highest charge capacity of 230 mC cm-2 among the electrodes. Electrical impedance spectroscopy was done to determine electrodes electrical behavior in different frequencies and find their characteristics quality as well.
https://www.ijnnonline.net/article_39979_40781d098494a550fa8de560869e61ec.pdf
2020-05-01
91
102
Carbon nanotubes
Composite materials
Energy Storages
Electrical properties.
S. A.
Hosseini
sahosseini@eng.ikiu.ac.ir
1
Department of Electrical Engineering, Faculty of Engineering, Imam Khomeini International University, Qazvin, Iran.
LEAD_AUTHOR
M.
Saghafi
msaghafi@eng.ikiu.ac.ir
2
Department of Materials Science and Engineering, Faculty of Engineering, Imam Khomeini International University, Qazvin, Iran.
AUTHOR
H.
Abiri
hamedabiri@ut.ac.ir
3
Department of Electrical Engineering, Faculty of Engineering, University of Tehran, Tehran, Iran.
AUTHOR
Saengchairat, N., Tran, T., Chua, C.-K., (2017). "A review: Additive manufacturing for active electronic components", Virtual Physical Prototyping, 12: 31-46.
1
Jokar, E., Shahrokhian, S., (2015). "Synthesis and characterization of NiCo 2 O 4 nanorods for preparation of supercapacitor electrodes", Journal of Solid State Electrochemistry, 19: 269-274.
2
Mohammad-Rezaei, R., Razmi, H., (2016). "Preparation and characterization of reduced graphene oxide doped in sol-gel derived silica for application in electrochemical double-layer capacitors", International Journal of Nanoscience, 12: 233-241.
3
Wessells, C. D., et al., (2011). "Nickel hexacyanoferrate nanoparticle electrodes for aqueous sodium and potassium ion batteries", Nano letters, 11: 5421-5425.
4
Chen, Y., et al., (2013). "Synthesis of carbon coated Fe3O4/SnO2 composite beads and their application as anodes for lithium ion batteries", Materials Technology, 28: 254-259.
5
Huang, F., et al., (2011). "Nanosized Zn–Sn metal composite oxide: a new anode material for Li ion battery", Materials Science and Technology, 27: 29-34.
6
Khorasani-Motlagh, M., Noroozifar, M., Yousefi, M., (2011). "A simple new method to synthesize nanocrystalline ruthenium dioxide in the presence of octanoic acid as organic surfactant", International Journal of Nanoscience Nanotechnology, 7: 167-172.
7
Zhang, S., Chen, G. Z., (2008). "Manganese oxide based materials for supercapacitors", Energy Materials, 3: 186-200.
8
Purushothaman, K., et al., (2017). "Design of additive free 3D floral shaped V2O5@ Ni foam for high performance supercapacitors", Materials technology, 32: 584-590.
9
Liu, Y., et al., (2013). "Graphene and nanostructured Mn3O4 composites for supercapacitors", Integrated Ferroelectrics, 144: 118-126.
10
Tan, D. Z. W., et al., (2014). "Controlled synthesis of MnO2/CNT nanocomposites for supercapacitor applications", Materials Technology, 29: A107-A113.
11
Jiang, X., et al., (2018). "Facile preparation of a novel composite Co-Ni (OH) 2/carbon sphere for high-performance supercapacitors", Materials Technology, 1-9.
12
Hosseini, M., et al., (2015). "Study of super capacitive behavior of polyaniline/manganese oxide-carbon black nanocomposites based electrodes", International Journal of Nanoscience Nanotechnology, 11: 147-157.
13
Zhang, Z., et al., (2016). "Mental-organic framework derived CuO hollow spheres as high performance anodes for sodium ion battery", Materials Technology, 31: 497-500.
14
Moosavifard, S. E., et al., (2014). "Facile synthesis of hierarchical CuO nanorod arrays on carbon nanofibers for high-performance supercapacitors", Ceramics International, 40: 15973-15979.
15
16. Prasad, K. P., et al., (2011). "Fabrication and textural characterization of nanoporous carbon electrodes embedded with CuO nanoparticles for supercapacitors", Science and Technology of Advanced Materials, 12: 044602.
16
Kim, T., et al., (2016). "Synthesis and characterization of NiCo2O4 nanoplates as efficient electrode materials for electrochemical supercapacitors", Applied Surface Science, 370: 452-458.
17
Zhang, J., et al., (2015). "Flower-like nickel–cobalt binary hydroxides with high specific capacitance: Tuning the composition and asymmetric capacitor application", Journal of Electroanalytical Chemistry, 743: 38-45.
18
Saghafi, M., et al., (2015). "Preparation of Co-Ni oxide/vertically aligned carbon nanotube and their electrochemical performance in supercapacitors", Materials and Manufacturing Processes, 30: 70-78.
19
Liu, X., et al., (2016). "Facile synthesis of Cu3Mo2O9@ Ni foam nano-structures for high-performance supercapacitors", Materials Technology, 31: 653-657.
20
Wang, R., et al., (2017). "Nanoporous Cu/Co alloy based Cu2O/CoO nanoneedle arrays hybrid as a binder-free electrode for supercapacitors", Journal of Materials Science: Materials in Electronics, 28: 8755-8763.
21
Tang, Y.-L., Hou, F., Zhou, Y., (2016). "Preparation and electrochemical performances of CoχNi (1− χ)(OH) 2 coated carbon nanotube free standing films as flexible electrode for supercapacitors", Materials Technology, 31: 377-383.
22
Yin, J., Park, J. Y., (2014). "Electrochemical investigation of copper/nickel oxide composites for supercapacitor applications", International Journal of Hydrogen Energy, 39: 16562-16568.
23
Nwanya, A. C., et al., (2017). "Nanoporous copper-cobalt mixed oxide nanorod bundles as high performance pseudocapacitive electrodes", Journal of Electroanalytical Chemistry, 787: 24-35.
24
Zhang, L., Gong, H., (2017). "Unravelling the correlation between nickel to copper ratio of binary oxides and their superior supercapacitor performance", Electrochimica Acta, 234: 82-92.
25
Fu, H., et al., (2015). "Electrochemical deposition of mesoporous NiCo2O4 nanosheets on Ni foam as high-performance electrodes for supercapacitors", Materials Research Innovations, 19: S255-S259.
26
Wu, C., et al., (2017). "Hybrid Reduced Graphene Oxide Nanosheet Supported Mn–Ni–Co Ternary Oxides for Aqueous Asymmetric Supercapacitors", ACS applied materials & interfaces, 9: 19114-19123.
27
Kim, N.-I., et al., (2016). "Enhancing activity and stability of cobalt oxide electrocatalysts for the oxygen evolution reaction via transition metal doping", Journal of The Electrochemical Society, 163: F3020-F3028.
28
Xu, Y.-T., et al., (2015). "Co-reduction self-assembly of reduced graphene oxide nanosheets coated Cu2O sub-microspheres core-shell composites as lithium ion battery anode materials", Electrochimica Acta, 176: 434-441.
29
Zhang, J., et al., (2018). "Synthesis of 3D porous flower-like NiO/Ni6 MnO8 composites for supercapacitor with enhanced performance", Journal of Materials Science: Materials in Electronics, 29: 7510-7518.
30
Pawar, S. M., et al., (2016). "Multi-functional reactively-sputtered copper oxide electrodes for supercapacitor and electro-catalyst in direct methanol fuel cell applications", Scientific reports, 6: 21310.
31
Sekar, N., Ramasamy, R. P., (2013). "Electrochemical impedance spectroscopy for microbial fuel cell characterization", J Microb Biochem Technol S, 6: 12-23.
32
ORIGINAL_ARTICLE
Numerical Simulation of MHD Boundary Layer Stagnation Flow of Nanofluid over a Stretching Sheet with Slip and Convective Boundary Conditions
An investigation is carried out on MHD stagnation point flow of water-based nanofluids in which the heat and mass transfer includes the effects of slip and convective boundary conditions. Employing the similarity variables, the governing partial differential equations including continuity, momentum, energy, and concentration have been reduced to ordinary ones and solved by using Keller-Box method. The behavior of emerging parameters is presented graphically and discussed for velocity, temperature, and nanoparticles fraction. The numerical results indicate that for the stretching sheet, the velocity at a point decreases with the increase in the values of and M; whereas both temperature and nanoparticle concentration increase with the increase in velocity slip parameter ( , magnetic parameter (M) and convective parameter ( . And also, observed that the velocity profile increases with the increase in velocity ratio parameter.
https://www.ijnnonline.net/article_39980_23046f0cea217455350275f4aa768f4d.pdf
2020-05-01
103
115
MHD
Stretching Sheet
nanofluid
Velocity Slip
Convective boundary condition.
D.
Ramya
ramya_ou@yahoo.com
1
Department of Mathematics, University College of Science, Osmania University, Hyderabad, 500007, Telangana, India.
LEAD_AUTHOR
J. A.
Rao
2
Department of Mathematics, University College of Science, Osmania University, Hyderabad, 500007, Telangana, India.
AUTHOR
I.
Shravani
3
Department of Mathematics, Government Degree College, Adilabad, 504001, Telangana, India.
AUTHOR
1. Sakiadis B. C., (1961). "Boundary-layer behavior on continuous solid surface: I. Boundary-layer equations for two-dimensional and axisymmetric flow", American Inst. Chemical Eng. J., 7: 26-28.
1
2. Crane L. J., (1970). "Flow past a stretching plate", Zeitschrift für angewandte Mathematik und Physik, 21(4): 645-647.
2
3. Gupta P. S., Gupta A. S., (1977). "Heat and mass transfer on a stretching sheet with suction or blowing", The Canadian J. Chem. Eng., 55: 744-746.
3
4. Cortell R., (2007). "Viscous flow and heat transfer over a nonlinearly stretching sheet", Appl. Math. Comput., 184: 864-873.
4
5. Subhas A., Veena P., (1998). "Visco-elastic fluid flow and heat transfer in a porous medium over a stretching sheet", Int. J. Non-Linear Mech., 33(3): 531-540.
5
6. Choi S. U. S., (1995). "Enhancing thermal conductivity of fluids with nanoparticles", ASME Int. Mech. Eng. Congress. San Francisco, USA, ASME, FED, 231/MD., 66: 99-105.
6
7. Sheikholeslami M., Gorji-Bandpy M., Ganji D. D., (2013)."Numerical investigation of MHD effects on Al2O3-water nanofluid flow and heat transfer in a semi-annulus enclosure using LBM", Energy, 60: 501-510.
7
8. Hamad M. A. A., Ferdows M., (2012). "Similarity solutions to viscous flow and heat transfer of nanofluid over nonlinearly stretching sheet",Appl. Math. Mech., 33: 923-930.
8
9. Rana P., Bhargava R., (2012). "Flow and heat transfer of a nanofluid over a nonlinearly stretching sheet: a numerical study", Commun. Nonlinear Sci. Numer. Simul., 17: 212-226.
9
Makinde O. D., Aziz A., (2011). "Boundary layer flow of a nanofluid past a stretching sheet with a convective boundary condition", Int. J. Thermal Sci., 50: 1326-1332.
10
Rashidi M. M., Vishnu Ganesh M., Abdul Hakeem A. K, Ganga B., (2014). "Buoyancy effect on MHD flow of nanofluid over a stretching sheet in the presence of thermal radiation", J. Molecular Liq., 198: 234-238.
11
Sheikholeslami M., Houman B. R., (2018). "CVFEM for effect of Lorentz forces on nanofluid flow in a porous complex shaped enclosure by means of non-equilibrium model", J. Molecular Liq., 254: 446-462.
12
Hiemenz V. K., (1911). "Die Grenzschicht an einem in den gleichförmigen Flüssigkeitsstrom eingetauchten geraden Kreiszylinder", Polytech. J., 326: 321-324.
13
Akbar N. S., Nadeem S., Rizwan Ul Haq, Khan, Z. H., (2013). "Radiation effects on MHD stagnation point flow of nano fluid towards a stretching surface with convective boundary condition", Chinese J. Aeronautics, 26(6): 1389-1397.
14
Bhatti M. M.,Ali Abbas M., Rashidi M. M., (2018), "A robust numerical method for solving stagnation point flow over a permeable shrinking sheet under the influence of MHD", Appl. Math. Comput., 316: 381-389.
15
Bhattacharyya K., Layek G. C., (2011). "Effects of suction/blowing on steady boundary layer stagnation-point flow and heat transfer towards a shrinking sheet with thermal radiation", Int. J. Heat Mass Transf., 54: 302-307.
16
Ibrahim W., Shankar B., Mahantesh N., (2013). "MHD stagnation point flow and heat transfer due to nanofluid towards a stretching sheet", Int. J. Heat Mass Transf., 56: 1-9.
17
Bachok N., Ishak A., Pop I., (2011). "Stagnation-point flow over a stretching/shrinking sheet in a nanofluid", Nanoscale Res. Letters, 6: 623.
18
Sheikholeslami M., Houman B. R., (2018). "Magnetic nanofluid flow and convective heat transfer in a porous cavity considering Brownian motion effects", Phys. Fluids, 30: 012003.
19
Sachin Shaw, Kameswaran P. K., Sibanda P., (2016). "Effects of slip on nonlinear convection in nanofluid flow on stretching surfaces", Boundary Value Prob., 2: 2016.
20
Samir Kumar Nandy, Tapas Ray Mahapatra, (2013). "Effects of slip and heat generation/absorption on MHD stagnation flow of nanofluid past a stretching/shrinking surface with convective boundary conditions", Int. J. Heat Mass Transf., 64: 1091-1100.
21
Kai-LongHsiao, (2016). "Stagnation electrical MHD nanofluid mixed convection with slip boundary on a stretching sheet", Appl. Thermal Eng.,98: 850-861.
22
Mustaffa M., Hina S., Hayat. T., Alsaedi, A., (2013). "Slip effects on the peristaltic motion of nanofluid in channel with wall properties", J. Heat Transf., 135.
23
Malvandi A., Hedayati F., Ganji D. D., (2014). "Slip effects on unsteady stagnation flow of nanofluid over a stretching sheet", Powder Technol., 253: 377-384.
24
Sheikholeslami M., Milad D., Sadoughi M. K., (2018). "Heat transfer improvement and pressure drop during condensation of refrigerant-based nanofluid; an experimental procedure", Int. J. Heat Mass Transf., 122: 643-650.
25
Sheikholeslami M., Ghasemi A., (2018). "Solidification heat transfer of nanofluid in existence of thermal radiation by means of FEM", Int. J. Heat Mass Transf., 123: 418-431.
26
Sheikholeslami M., (2018). "Numerical investigation for CuO-H2O nanofluid flow in a porous channel with magnetic field using mesoscopic method", J. Molecular Liq., 249: 739-746.
27
Sheikholeslami M., Mohadeseh S. N., (2018). "Simulation of nanofluid flow and natural convection in a porous media under the influence of electric field using CVFEM", Int. J. Heat Mass Transf., 120: 772-781.
28
Sheikholeslami M., Shehzad S. A., (2018). "Simulation of water based nanofluid convective flow inside a porous enclosure via non-equilibrium model", Int. J. Heat Mass Transf., 120: 1200-1212.
29
Sheikholeslami M., Shehzad S. A., (2018). "Numerical analysis of Fe3O4-H2O nanofluid flow in permeable media under the effect of external magnetic source", Int. J. Heat Mass Transf., 118: 182-192.
30
Sheikholeslami M., Houman B. R., (2018). Numerical simulation for impact of Coulomb force on nanofluid heat transfer in a porous enclosure in presence of thermal radiation, Int. J. Heat Mass Transf., 118: 823-831.
31
Sheikholeslami M., Sadoughi M. K., (2018), "Simulation of CuO-water nanofluid heat transfer enhancement in presence of melting surface", Int. J. Heat Mass Transf., 116: 909-919.
32
Sheikholeslami M., Shamlooei M., Moradi R., (2018). "Fe3O4-Ethylene glycol nanofluid forced convection inside a porous enclosure in existence of Coulomb force", J. Molecular Liq., 249: 429-437.
33
Sheikholeslami M., (2018). "CuO-water nanofluid flow due to magnetic field inside a porous media considering Brownian motion", J. Molecular Liq., 249: 921-929.
34
Nadeem S., Rizwan Ul Haq, (2014). "Effect of Thermal Radiation for Magnetohydrodynamic Boundary Layer Flow of a Nanofluid Past a Stretching Sheet with Convective Boundary Conditions", J. Comput. Theoret. Nanosci., 11:1-9.
35
Gangaiah T., Saidulu, N., Venkata Lakshmi, A., (2019). "The Influence of Thermal Radiation on Mixed Convection MHD Flow of a Casson Nanofluid over an Exponentially Stretching Sheet", Int. J. Nanosci. Nanotechnol., 15(2): 83-98.
36
Ghozatloo A., Shariaty Niassar M., Rashidi A., (2017). "Effect of Functionalization Process on Thermal Conductivity of Graphene Nanofluids", Int. J. Nanosci. Nanotechnol., 13(1): 11-18.
37
Dodda Ramya, Srinivasa Raju R., Anand Rao J., Rashidi M. M., (2016). "Boundary layer Viscous Flow of Nanofluids and Heat Transfer Over a Nonlinearly Isothermal Stretching Sheet in the Presence of Heat Generation/Absorption and Slip Boundary Conditions", Int. J. Nanosci. Nanotechnol., 12(4): 251-268.
38
Sheikholeslami M., Mollabasi H., Ganji D. D., (2015). "Analytical Investigation of MHD Jeffery-Hamel Nanofluid Flow in Non-Parallel Walls", Int. J. Nanosci. Nanotechnol., 11(4): 241-248.
39
Zeinali Heris S., Nassan T. H. N., Noie S. H., "CuO/water Nanofluid Convective Heat Transfer Through Square Duct Under Uniform Heat Flux", Int. J. Nanosci. Nanotechnol., 7(3): 111-120.
40
Sahooli M., Sabbaghi S., Shariaty Niassar M., (2012). "Preparation of CuO/Water Nanofluids Using Polyvinylpyrolidone and a Survey on Its Stability and Thermal Conductivity", Int. J. Nanosci. Nanotechnol., 8(1): 27-34.
41
Hooshyar Z., Bardajee G. R., (2010). "Viscosity and Rheological Behaviour of Ethylene Glycol-Maghemite Nanofluids", Int. J. Nanosci. Nanotechnol., 6(3): 191-193.
42
Ibrahim W., (2017). "Magnetohydrodynamic (MHD) boundary layer stagnation point flow and heat transfer of a nanofluid past a stretching sheet with melting", Propul. Power Res., 6: 214-222.
43
Cebeci T., Pradshaw P., (1998). "Physical and Computational Aspects of Convective Heat Transfer". Springer, NewYork.
44
ORIGINAL_ARTICLE
Amido-Amino Clay Stabilized Copper Nanoparticles: Antimicrobial Activity and Catalytic Efficacy for Aromatic Amination
Amido-amino functionalized halloysite stabilized copper nanoparticles (aah-CuNPs) were synthesized through one-pot protocol by a wet chemical method using hydrazine as reducing agent. The nanocomposite formed was stable in dry ethanol. The composition and binding nature of the nanocomposite were studied using FT-IR, DRS-UV, EDAX and powder XRD techniques. The morphological features of the composite were obtained from HRSEM analysis. The thermal stability of the copper nanocomposites was studied using TGA analysis. The prepared nanocomposite displayed broad spectrum antimicrobial activity, and it was very effective in Ullmann aromatic amination reaction.
https://www.ijnnonline.net/article_39981_4abf671785a5ce9b399ede2710c9fb1c.pdf
2020-05-01
117
125
Amido-amino clay
Aromatic amination
Catalysis
Copper nanoparticles
Ullmann reaction.
A.
Shibana T
ananya.shibana96@gmail.com
1
Department of Chemistry, Pondicherry University, Pondicherry, PY 605014 India.
AUTHOR
J.
Raiza
jaculinraiza@gmail.com
2
Department of Inorganic Chemistry, University of Madras, Guindy Campus, Chennai, TN 600025 India.
AUTHOR
K.
Pandian
jeevapandian@yahoo.co.uk
3
Department of Inorganic Chemistry, University of Madras, Guindy Campus, Chennai, TN 600025 India.
LEAD_AUTHOR
Liu, S., Pestano, J. P. C., Wolf, C., (2007). “Regioselective copper-catalyzed C-N and C-S bond formation using amines, thiols and halobenzoic acids”, Synthesis, 22: 3519-3527.
1
Ayoman , E., Hossini, G., N. Haghighi, N., (2015). “Synthesis of CuO nanoparticles and study on their catalytic properties”, Int. J. Nanosci. Nanotechnol., 11: 63-70.
2
Rahimi, P., Hashemipour, H., Ehtesham Zadeh, M., Ghader, S., (2010). “Experimental investigation on the synthesis and size control of copper nanoparticle via chemical reduction method”, Int. J. Nanosci. Nanotechnol., 6: 144-149.
3
Shadrokh, Z., Yazdani, A., Eshghi, H., (2017). “Study on structural and optical properties of wurtzite Cu2ZnSnS4 nanocrystals synthesized via solvothermal method”, Int. J. Nanosci. Nanotechnol., 13: 359-366.
4
Ahmadi, R., Razaghian, A., Eivazi, Z., Shahidi, K., (2018). “Synthesis of Cu-CuO and Cu-Cu2O nanoparticles via electro-explosion of wire method”, Int. J. Nanosci. Nanotechnol., 14: 93-99.
5
Khorshidi, A. R., Sh. Shariati, Sh., (2016). “-OSO3H Functionalized mesoporous MCM-41 coated on Fe3O4 nanoparticles: an efficient and recyclable nano-catalyst for preparation of 3,2′-bisindoles”, Int. J. Nanosci. Nanotechnol., 12: 139-147.
6
Maleki, A., (2016). “Efficient synthesis of 2, 3-dihydroquinazolin-4(1H)-ones in the presence of ferrite/chitosan as a green and reusable nanocatalyst”, Int. J. Nanosci. Nanotechnol., 12: 215-222.
7
Keshipour, S., Kalam Khalteh, N., (2017). “Pd and Fe3O4 Nanoparticles supported on N-(2-aminoethyl)acetamide functionalized cellulose as an efficient catalyst for epoxidation of styrene”, Int. J. Nanosci. Nanotechnol., 13: 219-226.
8
Anaraki Firooz, A., (2018). “Mo-Doped SnO2 nanoparticles: a case study for selective epoxidation of cycloocten”, Int. J. Nanosci. Nanotechnol., 14: 159-163.
9
Crabbe, B. W., Kuehm, O. P., Bennettb, J. C., Hallett-Tapley, G. L., (2018). “Light-activated Ullmann homocoupling of aryl halides catalyzed using gold nanoparticle-functionalized potassium niobium oxides”, Catal. Sci. Technol., 8: 4907-4915.
10
Kunz, K., Scholz, U., Ganzer, D., (2003). “Renaissance of Ullmann and Goldberg reactions - progress in copper catalyzed C-N-, C-O- and C-S-coupling”, Synlett., 15: 2428-2439.
11
Shaughnessy, K. H., Ciganek, E., DeVasher, R. B., (2014). “Copper-catalysed amination of aryl and alkenyl electrophiles”, Org. React. 85: 1-668.
12
Hartwig, J. F., (2008). “Evolution of a fourth generation catalyst for the amination and thioetherification of aryl halides”, Acc. Chem. Res. 41: 1534-1544.
13
M. Cortes-Salva, M., Garvin, C., Antilla, J. C., (2011). “Ligand-free copper-catalyzed arylation of amidines”, J. Org. Chem., 76: 1456-1459.
14
Yang, X., Liu, H., Fu, H., Qiao, R., Jiang, Y., Zhao, Y., (2010). “Efficient Copper-Catalyzed Synthesis of 4-Aminoquinazoline and 2,4-Diaminoquinazoline Derivatives”, SynLett., 1: 101-106.
15
Wolf, C., Liu, S., Mei, X., August, A. T., Casimir, M. D., (2006). “Regioselective Copper-Catalyzed Amination of Bromobenzoic Acids Using Aliphatic and Aromatic Amines”, J. Org. Chem., 71: 3270-3273.
16
Kwong, F. Y., Klapars, A., Buchwald, S. L., (2002). “Copper-catalyzed coupling of alkylamines and aryl iodides: an efficient system even in an air atmosphere”, Org. Lett., 4: 581-584.
17
Jiao, J., Zhang, X.-R., Chang, N.-H., Wang, J., Wei, J.-F., Shi, X.-Y., Chen, Z.-G., (2011). “A facile and practical copper powder-catalyzed, organic solvent- and ligand-free Ullmann amination of aryl halides”, J. Org. Chem., 76: 1180-1183.
18
Zhang, Y., Yang, X., Yao, Q., Ma, D., (2012). “CuI/DMPAO-Catalyzed N-Arylation of Acyclic Secondary Amines”, Org. Lett., 14: 3056-3059.
19
Zhou, W., Fan, M., Yin, J., Jiang, Y., Ma, D., (2015). “CuI/Oxalic diamide catalyzed coupling reaction of (hetero)aryl chlorides and amines”, J. Am. Chem. Soc., 137: 11942-11945.
20
Gao, J., Bhunia, S., Wang, K., Gan, L., Xia, S., Ma, D., (2017). “Discovery of N-(Naphthalen-1-yl)-N′-alkyl Oxalamide Ligands Enables Cu-Catalyzed Aryl Amination with High Turnovers”, Org. Lett., 19: 2809-2812.
21
Chen, Y.-J., Chen, H.-H., (2006). “1,1,1-Tris(hydroxymethyl)ethane as a new, efficient, and versatile tripod ligand for copper-catalyzed cross-coupling reactions of aryl iodides with amides, thiols, and phenols”, Org. Lett., 8: 5609-5612.
22
Vandarkuzhali, S. A. A., Radha, N., Pandian, K., (2013). “Water Soluble Iron aminoclay for Catalytic Reduction of Nitrophenol”, Orient. J. Chem., 29: 661-665.
23
Ramya, R., Jaculin Raiza, A., Devi, S., Raghunathan, R., Pandian, K., (2014-2015). “Synthesis of aminoclay protected palladium nanoparticles and study its catalytic activity in organic synthesis”, Int. J. ChemTech Res., 7: 1297-1302.
24
Datta, K. K. R., Kulkarni, C., Eswaramoorthy, M., (2012). “Aminoclay: a permselective matrix to stabilize copper nanoparticles”, Chem. Commun., 46: 616-618.
25
Raji, M., Mekhzoum, M. E. M., el Kacem Qaiss, A., Bouhfid, R., (2016). “Nanoclay modification and functionalization for nanocomposites development: Effect on the structural, morphological, mechanical and rheological properties. In Nanoclay Reinforced Polymer Composites”, Springer, Berlin, Germany.
26
Luty´nski, M., Sakiewicz, P., Luty´nska, S., (2019). “Characterization of diatomaceous earth and halloysite resources of Poland”, Minerals, 9: 670; doi:10.3390/min9110670.
27
Zhang, P., Shao, C., Zhang, Z., Zhang, M., Mu, J., Guo, Z., Liu, Y., (2011). “In situ assembly of well-dispersed Ag nanoparticles (AgNPs) on electrospun carbon nanofibers (CNFs) for catalytic reduction of 4-nitrophenol”, Nanoscale, 3: 3357-3363.
28
Pinto, R. J. B., Neves, M. C., Neto, C. P., Trindade, T., (2013). “Composites of cellulose and metal nanoparticles: In Nanocomposites – New trends and developments”, Ebrahimi F., Ed., 2012, 73-96.
29
Liu, S., Hu, M., Zeng, T. H., Wu, R., Jiang, R., Wei, J., Wang, L., Kong, J., Chen, Y., (2012). “Lateral dimension-dependent antibacterial activity of graphene oxide sheets”, Langmuir, 28: 12364-12372.
30
ORIGINAL_ARTICLE
The Effect of Temperature and Acidity on Antimicrobial Activities of Pristine MWCNTs and MWCNTs-Arg
Carbon nanotubes (CNTs) have very promising applications for inhibition of microbial growth. The aim of this study is investigation and comparison of the effect of temperature and acidity on antimicrobial activities of pristine Multiwalled Carbon nanotubes (MWCNTs) and Multiwalled Carbon nanotubes-Arginine (MWCNTs-Arg). Minimum Inhibitory Concentration (MIC) and Minimum Bactericidal Concentration (MBC) were calculated in range of temperature (25, 37 and 42 ºC) and pH (4.2, 7.2, and 10) on Staphylococcus aureus. The results approved that pristine and functionalized MWCNTs have broad-spectrum antimicrobial activities against examined pathogen. Between these agents, MWCNTs-Arg and pristine MWCNTs and have the highest inhibitory activity on microbial growth, respectively. The MBC value of MWCNTs was improved by amino acid functionalization. The optimal pH for antimicrobial activity of pristine MWCNTs and MWCNTs-Arg are 4.2 and 7.2 and optimal temperatures are 42 ºC and 42 ºC, respectively. There is no change on optimal temperature of MWCNTs by this functionalization, but functionalization of MWCNTs by Arg enhanced its antimicrobial activity and led to change of optimal pH of MWCNTs for antimicrobial activity. This changes lead to suitable improvement of antimicrobial activity in neutral and biological pH.
https://www.ijnnonline.net/article_39982_f46a8330d3683a583a954e0e974eec57.pdf
2020-05-01
127
136
Antimicrobial
Arginine
MWCNTs
pH
Temperature.
H.
Zare-Zardini
hadizarezardini@gmail.com
1
Hematology and Oncology Research Center, Shahid Sadoughi Hospital, Shahid Sadoughi University of Medical Sciences and Health Services, Yazd, Iran.
AUTHOR
M.
Shanbedi
mehdishanbedi@gmail.com
2
Department of Chemical Engineering, Faculty of Engineering, Ferdowsi University of Mashhad, Mashhad, Iran.
AUTHOR
H.
Soltaninejad
hosoltaninejad@gmail.com
3
Department of Nano Biotechnology, Faculty of Biological Sciences, Tarbiat Modares University, Tehran 14115, Iran.
AUTHOR
M.
Mohammadzadeh
m1978mm1355@gmail.com
4
Department of Reproductive Biology, Yazd Reproductive Sciences Institute, Research and Clinical Center for Infertility, Shahid Sadoughi University of Medical Sciences, Yazd, Iran.
AUTHOR
A.
Amiri
amiri.2227@yahoo.com
5
Department of Mechanical Engineering, Texas A&M University, College Station, TX 77843, United States.
LEAD_AUTHOR
A. A.
Hamidieh
aahamidieh@tums.ac.ir
6
Pediatric Cell Therapy Research Center, Tehran University of Medical Sciences, Tehran, Iran.
AUTHOR
F.
Ferdowsian
ferdosianfarzad@yahoo.com
7
Department of Pediatrics, Shahid Sadoughi University of Medical Sciences, Yazd, Iran.
AUTHOR
A.
Alemi
alemi.ashraf@gmail.com
8
Abadan Faculty of Medical Sciences, Abadan, Iran
AUTHOR
S.
Hoseinkhani
saman_h@modares.ac.ir
9
Department of Nano Biotechnology, Faculty of Biological Sciences, Tarbiat Modares University, Tehran 14115, Iran.
LEAD_AUTHOR
F.
Fesahat
farzaneh.fesahat@gmail.com
10
Reproductive Immunology Research Center, Shahid Sadoughi University of Medical Sciences, Yazd, Iran.
AUTHOR
A.
Astani
astani_ir@yahoo.com
11
Department of Microbiology, Faculty of Medicine, Shahid Sadoughi University of Medical Sciences, Yazd, Iran.
AUTHOR
Lashkari, B., Dehestani, M., Khosravan, A., Dehestani, M., (2017), “Investigation of Molecular Selenium Adsorption to the Outer Surface of Single Wall Carbon Nanotubes”, Int. J. Nanosci. Nanotechnol., 13: 129-137.
1
Basir Jafari, S., Malekfar, R., Khadem, S. E. R., (2001). ”Radial Breathing Mode Frequency of Multi-Walled Carbon Nanotube Via Multiple-Elastic Thin Shell Theory”, Int. J. Nanosci. Nanotechnol., 7: 137-142.
2
Farhadian, N., (2011). “Transport of a Liquid Water-Methanol Mixture in a Single Wall Carbon Nanotube”, Int. J. Nanosci. Nanotechnol., 7: 173-182.
3
Maleki Dizaj, S., Mennati, A., Jafari, S., Khezri, K., Adibkia, K., (2015 ). “Antimicrobial activity of carbon-based nanoparticles”, Adv Pharm Bull, 5: 19-23:
4
Al-Jumaili, A., Alancherry, S., Bazaka, K., Jacob, M. V., (2017). “Review on the Antimicrobial Properties of Carbon Nanostructures”, Materials (Basel), 10: 1066-1071.
5
Zhang, M., Li, J., (2009). “Carbon nanotube in different shapes”. Mater Today, 12: 12-18.
6
Dong, L., Henderson, A., Field, C. A., (2012)”ntimicrobial Activity of Single-Walled Carbon Nanotubes Suspended in Different Surfactants”, J. Nanotechnol., 2012: 1-9.
7
Yu, L., Zhang, Y., Zhang, B., Liu, J., (2014). “Enhanced Antibacterial Activity of Silver Nanoparticles/Halloysite Nanotubes/Graphene Nanocomposites with Sandwich-Like Structure”, Scientific Reports, 4: 4551-4568.
8
Vardharajula, S. et al. , (2012). “Functionalized carbon nanotubes: biomedical applications”, Int J Nanomedicine, 7: 5361-5374.
9
Zhang, Y., Bai, Y., Yan, B., (2010). “Functionalized carbon nanotubes for potential medicinal applications”, Drug Discov Today, 15: 428-435.
10
Soleimani, M., Ghahraman Afshar, M., Sedghi, A., (2013). “Amino-Functionalization of Multiwall Carbon Nanotubes and Its Use for Solid Phase Extraction of Mercury Ions from Fish Sample”, ISRN Nanotechnology, 2013: 8-19
11
Avilés, F., Cauich-Rodríguez, J. V., Moo-Tah, L., May-Pat, A., Vargas-Coronado, R., (2009).“Evaluation of mild acid oxidation treatments for MWCNT functionalization”, Carbon, 47: 2970-2975.
12
Tan, S. H., Goak, J. C., Lee, N., Kim, J.-Y., Hong, S. C., (2007). “Functionalization of Multi-Walled Carbon Nanotubes with Poly(2-ethyl-2-oxazoline)”, Macromolecular Symposia, 249: 275-270.
13
Meng, J. et al., (2012). “Effects of long and short carboxylated or aminated multiwalled carbon nanotubes on blood coagulation”, PLoS One, 7: e38995-e38995.
14
Zhang, T. et al., (2017). “Systemic and immunotoxicity of pristine and PEGylated multi-walled carbon nanotubes in an intravenous 28 days repeated dose toxicity study”, Int J Nanomedicine, 12: 1539-1554.
15
Yu, J. et al., (2016).“Comparison of Cytotoxicity and Inhibition of Membrane ABC Transporters Induced by MWCNTs with Different Length and Functional Groups”, Environ Sci Technol, 50: 3985-3994.
16
Zardini, H. Z., Amiri, A., Shanbedi, M., Maghrebi, M., Baniadam, M., (2012). “Enhanced antibacterial activity of amino acids-functionalized multi walled carbon nanotubes by a simple method”, Colloid Surface B, 92: 196-202.
17
Li, B., Webster, T. J., (2018).“Bacteria antibiotic resistance: New challenges and opportunities for implant-associated orthopedic infections”, J. Orthop. Res., 36: 22-32.
18
Chokshi, A., Sifri, Z., Cennimo, D., Horng, H. “Global Contributors to Antibiotic Resistance” J. Glob. Infect Dis., 11: 36-42.
19
Chandler, C. I. R., (2019).“Current accounts of antimicrobial resistance: stabilisation, individualisation and antibiotics as infrastructure”, Palgrave Communications, 5: 53-60
20
Al-Jumaili, A., Alancherry, S., Bazaka, K., Jacob, M. V., (2017). “Review on the antimicrobial properties of carbon nanostructures”, Materials ,10:1066-1072
21
Dizaj, S. M., Mennati, A., Jafari, S., Khezri, K., Adibkia, K., (2015). “Antimicrobial activity of carbon-based nanoparticles”, Adv. Pharm. Bull., 5: 19-27.
22
Freitas, T. A., Mattos, A. B., Silva, B. V. M., Dutra, R. F., (2014).“Amino-functionalization of carbon nanotubes by using a factorial design: human cardiac troponin T immunosensing application”, Biomed. Res. Int., 2014: 929786.
23
Mallakpour, S., Zadehnazari, A., (2013). “Functionalization of multi-wall carbon nanotubes with amino acid and its influence on the properties of thiadiazol bearing poly(amide-thioester-imide) composites”, Synthetic Metals, 169: 1–11.
24
Mallakpour, S., Zadehnazari, A., (2013). “Functionalization of multiwalled carbon nanotubes with S-valine amino acid and its reinforcement on amino acid-containing poly(amide-imide) bionanocomposites”, High Perform Polym., 25: 966-979.
25
Zare-Zardini, H., Amiri, A., Shanbedi, M., Memarpoor-Yazdi, M., Asoodeh, A., (2013). “Studying of antifungal activity of functionalized multiwalled carbon nanotubes by microwave-assisted technique”, Surf. Interface Anal, 45:751-755.
26
Amiri, A. et al., (2012). “Efficient method for functionalization of carbon nanotubes by lysine and improved antimicrobial activity and water-dispersion”, Mater. Lett., 72: 153-156.
27
Zardini, H. Z., Amiri, A., Shanbedi, M., Maghrebi, M., Baniadam, M., (2012). “Enhanced antibacterial activity of amino acids-functionalized multi walled carbon nanotubes by a simple method”, Colloids Surf B Biointerfaces, 92: 196-202 .
28
Ménard-Moyon, C., Kostarelos, K., Prato, M., Bianco, A., (2010). “Functionalized Carbon Nanotubes for Probing and Modulating Molecular Functions”, Chemistry & Biology, 17: 107-115.
29
Esteban, P. P. et al., (2014).“Enhancement of the antimicrobial properties of bacteriophage-K via stabilization using oil-in-water nano-emulsions”, Biotechnol. Prog., 30: 932-944.
30
Pumera, M., Sasaki, T., Iwai, H., (2008). “Relationship between Carbon Nanotube Structure and Electrochemical Behavior: Heterogeneous Electron Transfer at Electrochemically Activated Carbon Nanotubes”, Chemistry – An Asian Journal, 3: 2046-2055.
31
Hsieh, H. S., Wu, R., Jafvert, C. T., (2014). “Light-independent reactive oxygen species (ROS) formation through electron transfer from carboxylated single-walled carbon nanotubes in water”, Environ Sci. Technol. ,48: 11330-11336 .
32
Kim, J. S., Yu, I. J. , (2014). “Single-wall carbon nanotubes (SWCNT) induce cytotoxicity and genotoxicity produced by reactive oxygen species (ROS) generation in phytohemagglutinin (PHA)-stimulated male human peripheral blood lymphocytes”, J. Toxicol Environ Health A, 77: 1141-1153.
33
ORIGINAL_ARTICLE
The Effect of Different Supports on the Characteristic and Catalytic Properties of Ni-Mo/Cs1.5H1.5PW12O40/S (S= SiO2 or Al2O3 or ASA) Nanocatalysts in Hydrocracking of n-decane
In this research, Ni-Mo/Cs1.5H1.5PW12O40/S (S=SiO2 or Al2O3 or ASA (amorphous silica alumina)) nanocatalysts with different supports were prepared via 2 steps with impregnation method and the effect of support on the characteristic and catalytic properties of the prepared samples was studied. The synthesized samples were characterized by X-ray diffraction (XRD), temperature programmed desorption (TPD), temperature programmed reduction (TPR), and energy dispersive X-ray spectroscopy (EDX). Morphology of the samples was studied by field emission scanning electron microscope (FE-SEM) and the surface area, pore volume and pore size of the catalysts were determined by BET (Brunauer-Emmett-Teller) method. In the XRD patterns of the prepared catalysts, the H3PW12O40 (HPW) phase was observed. The FE-SEM images showed that the synthesized particles were in nanoscale. The results of TPD studies indicated that moderate acidic sites of Al2O3 supported nanocatalyst was more than the others. The catalytic activity of the nanocatalysts in hydrocracking of n-decane indicated that Al2O3 supported nanocatalyst had the highest catalytic activity.
https://www.ijnnonline.net/article_39983_0b086238268ac313a5a9358917b172fb.pdf
2020-05-01
137
144
Heteropoly acid
nanocatalyst
Hydrocracking
Al2O3.
H.
Amirmoghadam
amirmoghadam272@gmail.com
1
Department of Chemistry, Science and Research Branch, Islamic Azad University, Tehran, Iran.
AUTHOR
H. R.
Aghabozorg
aghabozorghr@ripi.ir
2
Research Institute of Petroleum Industry, Tehran, Iran.
LEAD_AUTHOR
M.
Hossaini Sadr
sadr@azaruniv.edu
3
Department of Chemistry, Azarbaijan Shahid Madani University, Tabriz, Iran.
AUTHOR
F.
Salehirad
salehiradf@ripi.ir
4
Research Institute of Petroleum Industry, Tehran, Iran.
AUTHOR
A.
Irandoukht
irandoukhta@ripi.ir
5
Research Institute of Petroleum Industry, Tehran, Iran.
AUTHOR
Cui, Q., Zhou, Y., Wei, Q., Yu, G., Zhu, L., (2013). “Performance of Zr- and P-modified USY-based catalyst in hydrocracking of vacuum gas oil”, Fuel Processing Technology, 106: 439-446.
1
Looi, P. Y., Mohamed, A. R., Tye, C. T., (2012). “Hydrocracking of residual oil using molybdenum supported over mesoporous alumina as a catalyst”, Chemical Engineering Journal, 181–182: 717-724.
2
Eom, H. J., Lee, D. W., Kim, S., Chung, S. H., Hur, Y. G., Lee, K. Y., (2014). “Hydrocracking of extra-heavy oil using Cs-exchanged phosphotungstic acid (CsxH3-xPW12O40, x = 1-3) catalysts”, Fuel, 126: 263–270.
3
Jin, H., Guo, D., Sun, X., Sun, S., Liu, J., Zhu, H., Yang, G., Yi, X., Fang, W., (2013).“Direct synthesis, characterization and catalytic performance of non-sulfided Ni–CsxH3-xPW12O40/SiO2 catalysts for hydrocracking of n-decane”, Fuel, 112: 134-139.
4
Liu, L., Wang, B., Yonghua, D., Borgna, A., (2015). “Supported H4SiW12O40/Al2O3 solid acid catalysts for dehydration ofglycerol to acrolein: Evolution of catalyst structure and performancewith calcination temperatureLicheng”, Applied Catalysis A: General, 489: 32-41.
5
Frattini, L., Mark, I., Christopher, M. A., Wilson, K., Kyriakou, G., Lee, A. F., (2017). “Support enhanced α-pinene isomerization over HPW/SBA-15” Applied Catalysis B: Environmental, 200: 10–18.
6
Jin, H., Yi, X., Sun, S., Liu, J., Yang, G., Zhu, H., Fang, W., (2012). “Hydrocracking of n-decane over non-sulfided Ni-CsxH3-xPW12O40/Al2O3 catalysts”, Fuel Processing Technology, 97: 52-59.
7
De Mattos, F. C. G., De Carvalho, E. N. C. B., Freitas, E. F., De Paiva, M. F., Ghesti, G. F., De Macedo, J. L., Dias, S. C. L., Dias, J. A., (2017). “Acidity and Characterization of 12-Tungstophosphoric Acid Supported on Silica‑Alumina”, J. Braz. Chem. Soc., 28: 336-347.
8
Qiu, B., Yi, X. D., Lin, L., Fang, W.P., Wan, H.L., (2008). “The hydrocracking of n-decane over bifunctional Ni-H3PW12O40/SiO2 catalysts”, Catalysis Today, 131: 464-471.
9
Corma, A., Martinez, A., Martinez, C., (1996). “Acidic Cs+, NH4+, and K+ Salts of 12-Tungstophosphoric Acid as Solid Catalysts for Isobutane/2-butene Alkylatio”, Journal of Catalysis, 164: 422-432.
10
Narasimharao, K., Brown, D. R., Lee, A. F., Newman, A.D., Siril, P. F., Avener, S. J., (2007). “Structure–activity relations in Cs-doped heteropolyacid catalysts for biodiesel production”, Journal of Catalysis, 248: 226-234.
11
Ameen, M., Azizan, M. T, Ramli, A., Yusup, S., Yasir, M., (2016). “Physicochemical properties of Ni-Mo/γ-Al2O3 catalysts synthesized via sonochemical method”, Procedia Engineering, 148: 64-71.
12
Liu, H. P, Lu, G. Z., Guo, Y., Wang, Y.Q., Guo, Y. L., (2009). “Synthesis of mesoporous Pt/Al2O3 catalysts with high catalytic performance for hydrogenation of acetophenone”, Catalysis Communications, 10: 1324-1329.
13
Jiang, J., Dong, Z., Chen, H., Sun, J., Yang, Ch., Cao, F., (2013). “The Effect of Additional Zeolites in Amorphous Silica−Alumina Supports on Hydrocracking of Semirefined Paraffinic Wax”. Energy and Fuels, 27: 1035-1042.
14
Mastikhin, V. M., Kulikov, S. M., Nosov, A. V., Kozhevnikov, I. V., Mudrakovsky, I. L., Timofeeva, M. N., (1990). “1H and 31P MAS NMR studies of solid heteropolyacids and H3PW12O40 supported on SiO2”, Journal of Molecular Catalysis, 60: 65–70.
15
Maity, S. K., Ancheyta, J., Alonso Mohan, F., Rana, S., (2004). “Preparation, characterization and evaluation of Maya crude hydroprocessing catalysts”, catalysis Today, 98: 193-199.
16
Reina, T. R., Yeletsky, P., Bermúdez, J. M., Arcelus-Arrillaga, P., Yakovlev, V. A., Millan, M., (2016). “Anthracene aquacracking using NiMo/SiO2 catalysts in supercritical water conditions”, Fuel, 182: 740–748.
17
Amimoghadam, H., Hossaini Sadr, M., Aghabozorg, H.R., Salehirad, F., Irandoukht, A., (2018). “The effect of molybdenum on the characteristicsand catalytic properties of M/Cs1.5H1.5PW12O40/Al2O3 (M = Ni or/and Mo) nanocatalysts in the hydrocracking of n-decane”, Reaction Kinetics, Mechanisms and Catalysis, 125: 983–994.
18
Roussel, M., Lemberton, J., Guisnet, M., Cseri, T., Benazzi, E., (2003). “Mechanisms of n-decane hydrocracking on a sulfided NiW on silica-alumina catalyst”, Journal of Catalysis, 218: 427-437.
19