@article { author = {Mehrizad, A. and Gharbani, P.}, title = {Study on Catalytic and Photocatalytic Decontamination of (2-Chloroethyl) Phenyl Sulfide with Nano-TiO2}, journal = {International Journal of Nanoscience and Nanotechnology}, volume = {7}, number = {1}, pages = {48-53}, year = {2011}, publisher = {Iranian Nanotechnology Society}, issn = {1735-7004}, eissn = {2423-5911}, doi = {}, abstract = {Catalytic and photocatalytic reactions of (2-chloroethyl) phenyl sulfide (2-CEPS), a mimic of bis (2-chloroethyl)  sulfide (i.e. Sulfur mustard) were studied on the surfaces of titanium oxide. TiO2 nanoparticles (anatase, rutile and mixture of 80% anatase/20% rutile) along with bulk TiO2 were tested as reactive sorbents for reaction of 2-CEPS at room temperature (25±0.5°C). Reactions were monitored by GC-FID technique and reaction products were characterized by GC-MS. Data explores the role of hydrolysis and elimination reactions in the reaction of 2-CEPS on titanium oxide. In these reactions, 2-CEPS undergo photocatalytic reactions to yield  (2-hydroxyethyl) phenyl sulfide, (2-ethoxyethyl) phenyl sulfide and vinyl phenyl sulfide. Also data reveals that the maximum decontamination of 2-CEPS was related to nano-TiO2 (80% anatase/ 20% rutile)/ UV.}, keywords = {Catalytic,Photocatalytic,Decontamination,Nano-TiO2,(2-Chloroethyl) phenyl sulfide}, url = {https://www.ijnnonline.net/article_3953.html}, eprint = {https://www.ijnnonline.net/article_3953_36ac51e9dcbc099caa5d003b80f76258.pdf} }