@article { author = {Nasihat Sheno, N. and Morsali, A.}, title = {Synthesis of Different Copper Oxide Nano-Structures From Direct Thermal Decomposition of Porous Copper(ΙΙ) Metal-Organic Framework Precursors}, journal = {International Journal of Nanoscience and Nanotechnology}, volume = {8}, number = {2}, pages = {99-104}, year = {2012}, publisher = {Iranian Nanotechnology Society}, issn = {1735-7004}, eissn = {2423-5911}, doi = {}, abstract = {Copper oxide nanostructures have been successfully synthesized via one-step solid-state thermolysis of two metal-organic frameworks, [Cu3(btc)2] (1) and [Cu(tpa).(dmf)] (2), (btc = benzene-1,3,5-tricarboxylate, tpa = therephtalic acid = 1,4-benzendicarboxylic acid and dmf = dimethyl formamide) under air atmosphere at 400,  500, and 600°C. It has also been found that the reaction temperature plays a substantial role in the formation of copper oxide nanostructures. The obtained products were characterized by X-ray powder diffraction (XRPD),  Energy dispersive X-ray microanalysis (EDX), and scanning electron microscopy (SEM). Different reaction conditions were discussed. This study demonstrates that the metal-organic frameworks can be used as precursors for the preparation of nanoscale materials with difference and remarkable morphologies.}, keywords = {Metal-organic framework,Solid-state thermolysis,Nano-structures,Copper oxide}, url = {https://www.ijnnonline.net/article_3912.html}, eprint = {https://www.ijnnonline.net/article_3912_c92b9f3e462bf6d1e0703aa1c8a32317.pdf} }