International Journal of Nanoscience and Nanotechnology

International Journal of Nanoscience and Nanotechnology

Effects of Graphene Oxide Size on PES ‎Ultrafiltration Hydrophilicity and Pure ‎Water Flux

Document Type : Research Paper

Authors
Zahra Madanirad 1
Mahdi Akbari 1
Mojtaba Shariaty-Niassar 1
Karim Akbari Vakil Abadi 2
1 Transport Phenomena & Nanotech. Lab (TPNT), School of Chemical Engineering, ‎College of Engineering, University of Tehran, P.O. Box: 11155-4563, Tehran, Iran‎
2 Department of Mechanical Engineering, Imam Khomeini Naval University, Noshahr, Iran
10.22034/ijnn.2023.2001625.2372
Abstract
   In this study, the effects of graphene oxide (GO) size on the structure and performance of polyethersulfone/graphene oxide nanocomposite ultrafiltration membrane (prepared via phase inversion method) were studied. Graphene oxide was synthesized by Hummers method and was divided into two parts with different sizes (80 nm and 110 nm) by means of centrifugation (10000 rpm). Synthesized GO was characterized by FESEM, TEM, Raman spectroscopy, FTIR, XRD and DLS. Prepared membranes were characterized by FESEM, AFM, contact angle and pure water permeation flux. Interestingly, decrease in PWP permeance was observed with an increase in the concentration of smaller GO in the membrane, while the trend was reversed by the addition of the larger GO. As a result, the maximum PWP permeance of 21 kg/m2 h bar was achieved when the smaller GO concentration was 0.1 wt.% while 23 kg/m2 h bar was achieved when the larger GO concentration was 1 wt.%.  This opposite trend is ascribed to the readiness of smaller GO nanosheets to aggregate. The antifouling capacity of nanocomposite membranes was found to be higher than the pristine PES membrane.
Keywords
Graphene oxide
Polyethersulfone
Membrane
Phase inversion
Anti-fouling properties.‎

Subjects

  1. Sahinkaya, E., “Concentrate minimization and water recovery enhancement using pellet precipitator in a reverse osmosis process treating textile wastewater”,. Journal of Environmental Management, 222 (2018) 420-427.
  2. Jiang, S., Y. Li, Ladewig, B. P. “A review of reverse osmosis membrane fouling and control strategies”, Science of The Total Environment, 595 (2017) 567-583.
  3. Shi, X., “Fouling and cleaning of ultrafiltration membranes: A review”, Journal of Water Process Engineering, 1 (2014) 121-138.
  4. Yang, Y., “The influence of nano-sized TiO2 fillers on the morphologies and properties of PSF UF membrane”, Journal of Membrane Science, 288(1-2) (2007) 231-238.
  5. Zinadini, S., “Preparation and characterization of antifouling graphene oxide/polyethersulfone ultrafiltration membrane: Application in MBR for dairy wastewater treatment”, Journal of Water Process Engineering, 7 (2015) 280-294.
  6. Rakhshan, N., Pakizeh, M., “The effect of chemical modification of SiO2 nanoparticles on the nanofiltration characteristics of polyamide membrane”, Korean Journal of Chemical Engineering, 32(12) (2015) 2524-2533.
  7. Wang, Q., “Impact of sodium hypochlorite cleaning on the surface properties and performance of PVDF membranes”, Applied Surface Science, 428 (2018) 289-295.
  8. Rahimpour, A., Madaeni, S., “Polyethersulfone (PES)/cellulose acetate phthalate (CAP) blend ultrafiltration membranes: preparation, morphology, performance and antifouling properties”, Journal of Membrane Science, 305(1) (2007) 299-312.
  9. Qu, P., “Polyethersulfone composite membrane blended with cellulose fibrils”, BioResources, 5(4) (2010) 2323-2336.
  10. Vatanpour, V., “TiO2 embedded mixed matrix PES nanocomposite membranes: influence of different sizes and types of nanoparticles on antifouling and performance”, Desalination, 292 (2012) 19-29.
  11. Jin, F., “High-performance ultrafiltration membranes based on polyethersulfone–graphene oxide composites”, Rsc Advances, 3(44) (2013) 21394-21397.
  12. Van der Bruggen, B., “Chemical modification of polyethersulfone nanofiltration membranes: a review”, Journal of applied polymer science, 114(1) (2009) 630-642.
  13. Liu, Y., “Improved antifouling properties of polyethersulfone membrane by blending the amphiphilic surface modifier with crosslinked hydrophobic segments”, Journal of Membrane Science, 486 (2015) 195-206.
  14. Moghimifar, V., “Enhancing the antifouling property of polyethersulfone ultrafiltration membranes using NaX zeolite and titanium oxide nanoparticles”, RSC Advances, 5(69) (2015) 55964-55976.
  15. Amirilargani, M., Saljoughi, E., Mohammadi, T., “Effects of Tween 80 concentration as a surfactant additive on morphology and permeability of flat sheet polyethersulfone (PES) membranes”, Desalination, 249(2) (2009) 837-842.
  16. Farahani, M. H. D. A., Rabiee, H., Vatanpour, V., “Comparing the effect of incorporation of various nanoparticulate on the performance and antifouling properties of polyethersulfone nanocomposite membranes”, Journal of Water Process Engineering, 27 (2019) 47-57.
  17. Rahimpour, A., “UV photo-grafting of hydrophilic monomers onto the surface of nano-porous PES membranes for improving surface properties”, Desalination, 265(1) (2011) 93-101.
  18. Shi, Q., “Grafting short-chain amino acids onto membrane surfaces to resist protein fouling”, Journal of Membrane Science, 366(1) (2011) 398-404.
  19. Dave, H. K., Nath, K., “Graphene oxide incorporated novel polyvinyl alcohol composite membrane for pervaporative recovery of acetic acid from vinegar wastewater”, Journal of Water Process Engineering, 14 (2016) 124-134.
  20. Song, N., “A review of graphene-based separation membrane: Materials, characteristics, preparation and applications”, Desalination, 437 (2018) 59-72.
  21. Abdel-Karim, A., “High flux and fouling resistant flat sheet polyethersulfone membranes incorporated with graphene oxide for ultrafiltration applications”, Chemical Engineering Journal, 334 (2018) 789-799.
  22. Zhu, Z., “Preparation and characteristics of graphene oxide-blending PVDF nanohybrid membranes and their applications for hazardous dye adsorption and rejection”, Journal of colloid and interface science, 504 (2017) 429-439.
  23. Hu, X., “Effects of particle size and pH value on the hydrophilicity of graphene oxide”, Applied Surface Science, 273 (2013) 118-121.
  24. Shen, J., “Size effects of graphene oxide on mixed matrix membranes for CO2 separation”, AIChE Journal, (2016).
  25. Wang, G., “Synthesis of enhanced hydrophilic and hydrophobic graphene oxide nanosheets by a solvothermal method”, Carbon, 47(1) (2009) 68-72.
  26. Sun, H., Cao, L., Lu, L., “Magnetite/reduced graphene oxide nanocomposites: one step solvothermal synthesis and use as a novel platform for removal of dye pollutants”, Nano Research, 4(6) (2011) 550-562.
  27. Zinadini, S., “Preparation of a novel antifouling mixed matrix PES membrane by embedding graphene oxide nanoplates”, Journal of Membrane Science, 453 (2014) 292-301.
  28. Li, P., “Synthesis, characterization, and bactericidal evaluation of chitosan/guanidine functionalized graphene oxide composites”, Molecules, 22(1) (2016) 12.
  29. Rana, S., Maddila, S., Jonnalagadda, S. B., “Synthesis and characterization of Pd (II) dispersed over diamine functionalized graphene oxide and its scope as a catalyst for selective oxidation”, Catalysis Science & Technology, 5(6) (2015) 3235-3241.
  30. Ganesh, B., Isloor, A. M., Ismail, A., “Enhanced hydrophilicity and salt rejection study of graphene oxide-polysulfone mixed matrix membrane”, Desalination, 313 (2013) 199-207.
  31. Marcano, D. C., “Improved synthesis of graphene oxide”, ACS Nano, 4(8) (2010) 4806-4814.
  32. Zhang, L., “Size-controlled synthesis of graphene oxide sheets on a large scale using chemical exfoliation”, Carbon, 47(14) (2009) 3365-3368.
  33. Shin, H. J., “Efficient reduction of graphite oxide by sodium borohydride and its effect on electrical conductance”, Advanced Functional Materials, 19(12) (2009) 1987-1992.
  34. Park, S., “Hydrazine-reduction of graphite-and graphene oxide”, Carbon, 49(9) (2011) 3019-3023.
  35. Zhao, Y., “Performance enhancement of polyvinyl chloride ultrafiltration membrane modified with graphene oxide”, Journal of Colloid and Interface Science, 480 (2016) 1-8.
International Journal of Nanoscience and Nanotechnology
Volume 19, Issue 2
Spring 2023
Pages 121-134